Plastic laminated metallic foil and method for preparing the same

ABSTRACT

A plastic laminated metallic foil is prepared by laminating a first layer of a polymer selected from the group consisting of ethylene-unsaturated carboxylic acid copolymers, ethylene-unsaturated carboxylic acid ester copolymers, ethylene-unsaturated carboxylic acid-unsaturated carboxylic acid-ester ternary copolymers, ionomers containing these copolymers as the base, and graft copolymers of polyethylene and unsaturated carboxylic acids on at least one surface of a metallic foil, and further laminating a second layer of a polymer selected from the group consisting of polyethylene, ethylene-vinyl acetate copolymers, ethylene-unsaturated carboxylic acid ester copolymers, and graft copolymers of polyethylene and unsaturated carboxylic acid esters onto the first polymer layer of the metallic foil.

This is a continuation of application Ser. No. 93,784, filed Nov. 30,1970 now abandoned.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a plastic laminated metallic foil andmore particularly to a plastic laminated metallic foil, which exhibitsexcellent properties as a covering material and specifically,electrostatic shielding layer and moisture proofing layer forcommunication cable. A method for producing these foils is also anintegral part of the present invention.

2. Description of the Prior Art

In recent years, covering materials of the shielding type havingfavorable moisture proofness have been highly desired. In one instance,there is a shielded piece obtained by covering one surface of a metallicfoil with a polyolefin as disclosed in Japanese Patent Publication No.14350/1965 (now abandoned).

According to the invention of that patent publication, since theshielded piece is bonded to a jacket, when the cable is stretched orbent, the metallic foil and jacket are hardly broken. However, sinceshielded piece possesses but one layer of polyolefin, it is difficult tofirmly bond the polyolefin layer to both of the metallic foil and thejacket. As a result, when employing a polyolefin which adheres favorablywith the metallic foil, the jacket is extremely difficult to bond to thepolyolefin. On the other hand, when employing material other than apolyolefin which adheres favorably with the jacket, the metallic foilremains difficult to bond to the material.

Hence, satisfactory covering materials for communication cable leavemuch to be desired.

SUMMARY OF THE INVENTION

It is therefore the primary object of the present invention to eliminatethe above-mentioned disadvantages by utilizing certain findings whichthe present inventors have made and thereby produce a plastic laminatedmetallic foil having excellent adhesiveness between each of the layersas well as both surfaces of the plastic laminated foil.

It is another object of the present invention to provide a method forproducing the above-mentioned plastic laminated metallic foil.

Accordingly, the present invention provides a plastic laminated metallicfoil prepared by laminating a first layer of a polymer selected from thegroup consisting of ethylene-unsaturated carboxylic acid copolymers,ethylene-unsaturated carboxylic acid ester copolymers, ionomerscontaining these copolymers as the base, and graft copolymers ofpolyethylene and unsaturated carboxylic acids on at least one surface ofa metallic foil, and further laminating a second layer of a polymerselected from the group consisting of polyethylene, ethylene-vinylacetate copolymers, ethylene-unsaturated carboxylic acid estercopolymers, and graft copolymers of polyethylene and unsaturatedcarboxylic acid esters onto the first polymer layer of the metallicfoil. All of these copolymers should preferably have a molecular weightin the range of from 10,000-50,000. However, this is not mandatory.

The nature, details, and utility of the present invention will be madeclearer from the following detailed description.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross-sectional view showing the plastic laminated metallicfoil according to the present invention in which the plastic films arelaminated on only one side of the metallic foil;

FIG. 2 is a sectional view showing the plastic laminated metallic foilaccording to the present invention in which the plastic films arelaminated on both sides of the metallic foil; and

FIG. 3 is a sectional view showing an instance in which the plasticlaminated metallic foil according to this invention is employed as ashielding layer for a communication cable.

DETAILED DESCRIPTION OF THE INVENTION

As the metallic foils to be employed in the present invention, thereare, for example, aluminum, copper, iron, steel, silver, gold, tinfoils, aluminum and copper foils.

As the copolymers of ethylene and unsaturated carboxylic acids, thereare, for example, copolymers obtained from ethylene and mono- ordi-valent unsaturated aliphatic carboxylic acids containing 2-12 carbonatoms (except for these carbons in the carboxylic groups), andparticularly, acrylic acid, methacrylic acid, itaconic acid, and maleicanhydride. Furthermore, ternary copolymers consisting of ethylene, theabove-described unsaturated carboxylic acids, and the carboxylic estersthereof may also be employed. As the esters in these copolymers, thereare ethyl acrylate, propyl acrylate, butyl acrylate, ethyl methacrylatepropyl methacrylate, and butyl methacrylate. In this case, it isdesirable to use no more than 20 wt. % of the ester with respect to theamount of ethylene. In cases where the amount of the ester employed ismore than 20 wt. % with respect to that of the ethylene, its adhesion topolyethylene, ethylene-vinyl acetate copolymer, etc. is extremelydiminished. Furthermore, in this case, there may be employed ionomerresins obtained in such a manner that the above-mentioned copolymers areemployed as base resin, and a metal cation is caused to combinetherewith, whereby the copolymer molecules are cross-linked by the ionicbonding force of carboxylic anion with metal cation. (See JapanesePatent Publication No. 6810/1964). In this case, as the metal cationscontemplated, there are ionizable organic or inorganic metal salts.Illustrative of these are magnesium acetate, strontium hydroxide, sodiumhydroxide, and zinc acetate. The metal salt is employed in an amountsufficient for neutralizing at least 10% of the carboxylic acid. Forexample, there is "Saline A-1602," manufactured by DuPont Co.,Furthermore, graft copolymers of polyethylene and the above-mentionedunsaturated carboxylic acids may be also used. Regarding theabove-mentioned copolymers (including graft copolymers), a copolymerconsisting of 50-98 wt. % of ethylene and 50-2 wt. % of carboxylic acidor carboxylic acid and carboxylic acid ester is favorable, andparticularly, one consisting of 70-90 wt. % of ethylene and 30-10 wt. %of carboxylic acid or carboxylic acid and carboxylic acid ester ispreferred. In the case where the ethylene content is greater than 98 wt.%, the adhesiveness with respect to metallic foil becomes insufficient.On the other hand, when the ethylene content is less than 50 wt. %, theadhesiveness of the ethylene with respect to the second layer ofpolyethylene, ethylene-vinyl acetate copolymer, or ethylene-unsaturatedcarboxylic acid ester copolymer becomes inferior.

The effects of the ethylene-vinyl acetate copolymer used in the presentinvention is good when the amount of vinyl acetate is no more than 30%by weight in content. A range of 2 to 20% by weight is particularlyexcellent. When it is more than 30% by weight, the adhesion to thecovering jacket (i.e., polyethylene), is undesirably lowered.

The ester in the ethylene-unsaturated carboxylic ester employed in thepresent invention is an ethyl, propyl, or butyl ester of unsaturatedcarboxylic acids as described above. The amount of unsaturatedcarboxylic ester present in the copolymer is preferably no more than 95%by weight and most preferably 1 to 85% by weight. In case it is morethan 95% by weight, the adhesion of the copolymer to the covering jacketis undesirably lowered. As the graft copolymers of polyethylene and theabove-mentioned unsaturated carboxylic esters, there are, for example,"Bakelite DPDB-6169," manufactured by the Union Carbide Co. In general,the amount of ester employed in the graft copolymer is preferably nomore than 70% by weight, and most preferably 10 to 70% by weight. In theplastic laminated metallic foil according to the present invention, theadhesion treatment may be carried out in such a manner that the surfaceof the outer plastic layer which does not come into contact with thefirst layer is treated by commonly known methods. Illustrative of theseare corona discharge, oxidizing flame, and chromic acid.

In the case where the plastic laminated metallic foil according to thisinvention is employed as a covering layer for cable, the thickness ofthe metallic foil should be about 100-250 μ. The thickness of doublelayer plastic film should be about 45-75 μ, and in this case, it ispreferred that the thickness of the outer (second) layer (e.g.,polyethylene) be about 20-30 μ. Of course, these thicknesses mentionedabove will vary in accordance with the purpose for which the plasticlaminated metallic foil according to this invention is employed.

Since the second plastic layer of the plastic laminated metallic foilaccording to this invention has excellent adhesiveness with respect topolyolefins (e.g., polyyethylene, polypropylene, and polyolefincontaining less than 5 wt. % of vinyl chloride or vinyl acetate)employment of the plastic laminated metallic foil of the presentinvention as a shielding layer for communication cable provides anexcellent communication cable. This is especially true wherepolyethylene is employed as the jacket cover.

In the following, the plastic laminated metallic foil according to thisinvention will be described in connection with the accompanying drawing.

DETAILED DESCRIPTION OF THE DRAWINGS

In FIGS. 1 and 2, reference numeral 1 designated a second layer ofpolyethylene, ethylene-vinyl acetate copolymer, or ethylene-unsaturatedcarboxylic acid copolymer, 2, a first layer of an ethylene-unsaturatedcarboxylic ester copolymer, etc., 3 a metallic foil, and 4 an adhesiontreatment layer, respectively.

FIG. 3 is a sectional view illustrating the case in which the plasticlaminated metallic foil according to the present invention is employedas a shielding layer for communication cable in which reference numeral5 designates an assembled core, 6 a bundled layer of polyester film orsynthetic rubber tape, 7 the plastic laminated metallic foil of thisinvention, 8 an outer surface plastic jacket, and 9 an adhered portionof the metallic foil of the plastic laminated metallic foil and thesurface of the polymer, respectively. The adhesion of this adheredportion is particularly excellent in the case where the plasticlaminated metallic foil of this invention is employed.

Next, a method for producing the plastic laminated metallic foil of thisinvention will be described.

A double layer plastic film can be obtained in such a manner that twofilm layers previously formed separately are caused to adhere to eachother by means of thermally pressing adhesion or by employment of anadhesive. Either method, however, leaves much to be desired. This is dueto the fact that the adhesiveness between both layers is insufficient ineither case. Furthermore, the number of process steps are great. Inorder to obtain the double layer plastic film of the plastic laminatedmetallic foil of the present invention, a multilayer extrusion processis the most suitable method. That is, by the multilayer extrusionprocess, two kinds of polymers forming the first and second layers beingseparately molten, are extruded as two streams. These two streams areintroduced into a single die to form a single fluid consisting of eachlayer of the two polymers in its molten state, and the single fluid thusobtained is extruded from the die, thereby providing an integrated filmof the two kinds of polymers.

For the extruding machine applicable, an inflation extruding machine anda T-die inflation extruding machine, etc. are generally contemplated foruse in the present invention.

The adhesion of different layers of the composite plastic film thusobtained is complete and it is difficult to mechanically tear off thesetwo film layers.

In the following, one example of the method for producing the plasticlaminated metallic foil according to this invention will be described.

First of all, in preparing the above-mentioned multilayer extrusioncomposite plastic film, either or both surfaces of the composite plasticfilm are subjected to adhesion treatment by corona discharge, oxidizingflame, or chemicals. Particularly, corona discharge is preferred. Thethus treated composite plastic film is thermally pressed with a metallicfoil. The thermally pressing adhesion step is carried out in such amanner that the plastic film is heated so as to soften the surfacethereof. It is further pressed under a pressure of 1-10 kg/cm² at atemperature of 80°-150° C, and then, the resulting laminated plasticfilm is subjected to heat treatment at a temperature of 150°-220° C for30 seconds to 5 minutes.

The surface treatment of the seamed layer may be carried out subsequentto thermal pressing of the plastic film with metallic foil.

In the plastic laminated metallic foil thus obtained, the surfaces ofdifferent plastics of the multilayer extrusion composite plastic filmare completely bonded, so that the both surfaces of the plastics cannotbe torn off manually. Furthermore, the adhesion of the metallic foil andthe multilayer extrusion composite plastic film is unexpectablyfavorable.

Moreover, in the case where the plastic laminated metallic foil isemployed as a shielding material for communication cable, the adhesionof the communication cable with the outer polyolefin covering (usuallypolyethylene) is unexpectably favorable, because the adhesion is madethrough the surface of the ethylene-unsaturated carboxylic estercopolymer.

For this reason, when the plastic laminated metallic foil according tothe present invention (having a metallic foil on one side and amultilayer extrusion composite plastic film on another side thereof) isemployed, for example, as a shielding material for communication cableand capacitor thin film, favorable results are attained due to theexcellent bonding between the outer plastic surface and the innermetallic foil surface.

Furthermore, since the plastic laminated metallic foil of this inventionhas a layer of polyethylene, ethylene-vinyl acetate copolymer, orethylene-unsaturated carboxylic ester copolymer on the surface of anethylene-unsaturated carboxylic acid copolymer (which is normallyinferior in water resistance, moisture proofness, and adhesiveness withrespect to the outer plastic jacket), an excellent electricallyinsulated water and moisture proof layer can be attained by the adoptionof the second plastic layer. This layer also imparts mechanical strengthto the metallic foil as well.

When the plastic laminated metallic foil of this invention is employedfor communication cable, in the case of bending and stretching of thecable, the metallic foil, double layer plastic film, and plastic jacketmove simultaneously, so that they are not torn off with each other.Accordingly, there is no fear of breaking the shielding layer.

As mentioned above, since the plastic laminated metallic foil accordingto this invention has excellent water resistance properties, moistureproofness, shielding effect, and mechanical strength, the plasticlaminated metallic foil may not only be used in the air, but also ascommunication cable.

In addition to its use as covering material for communication cable, thelaminated film of the present invention may also be used for packagingmaterials and thin films for condensers as well.

A better understanding of the present invention will be attained fromthe following examples, which are merely intended to be illustrative andyet not limitative of the present invention.

In the following examples, each composite film obtained by multilayerextrusion was prepared in such a manner that both materials of two kindsof films were heated to a temperature of about 100° to 200° C higherthan the softening point of each material, respectively. They were thenheated at a higher temperature of 10° to 50° C at the vicinity of theoutlet of a die and were extruded. The composite film was substantially0.05 mm in thickness and one sheet of film was about 0.025 mm, itsextruding amount being 0.1-10 kg/hr.

EXAMPLES 1-6 and Reference Examples 1-3

A double layer of plastic film having a width of 10 cm and a thicknessof 0.05 mm as shown in Table 1 was prepared. Soft aluminum having awidth of 10 cm and a thickness of 0.2 mm was laminated on the doublelayer plastic film in a hot blast stove at a temperature of 180° C usinga 5 kg load roller.

The adhesiveness between the metallic foil and the plastic film of theresulting plastic laminated metallic foil was measured (A-method).

On the other hand, polyethylene (0506 manufactured by Nitto Unicar Co.)used for the outer polyethylene jacket of a communication cable wasformed into a sheet having a thickness of 2 mm. The sheet was heated ina hot blast stove at a temperature of 180° C for 10 minutes. The soheated sheet was superimposed on the plastic surface of the abovedescribed plastic laminated metallic foil in the stove and press bondedby one reciprocating motion of a 5 kg load roller. The adhesivenessbetween the polyethylene and the plastic laminated metallic foil wasmeasured (B-method).

The measurement of adhesiveness was carried out by a tearing test undera condition of a temperature of 20° C and a stretching speed of 200mm/min. at 180° C, respectively.

The results of the test are shown in the following Table 1.

                                      TABLE 1                                     __________________________________________________________________________                               Results of Test                                           Plastic Film        A-Method                                                                            B-Method                                            First Layer                                                                             Second Layer                                                                            g/10 cm                                                                             g/10 cm                                      __________________________________________________________________________    Example 1                                                                            Saline A-1650                                                                           Ethylene-Vinyl                                                      Ionomer con-                                                                            Acetate (Eva-                                                       taining an ethy-                                                                        plex-660, manu-                                                     lene-acrylic acid                                                                       factured by Mit-                                                                        720   3030                                                copolymer as a                                                                          sui Polychemi-                                                      base and obtained                                                                       cals Co.) (Vinyl                                                    by using a Zn                                                                           Acetate 8 wt.%                                                      salt M.I. = 2.0                                                                         M.I. = 2.0)                                                  Example 2                                                                            Saline A-1601                                                                           Evaplex-560                                                         ionomer con-                                                                            (Vinyl Acetate)                                                     taining an ethy-                                                                        14 wt. % M.I. =                                                     lene-acrylic                                                                            3.5       600   2080                                                acid copolymer                                                                as a base and                                                                 obtained by using                                                             Na salt M.I. =1.2                                                      Example 3                                                                            Ethylene-Acrylic                                                                        Polyethylene                                                        Acid Copolymer                                                                          (Corona treated                                                     (Acrylic acid 14                                                                        surface)  550   1200                                                wt.%, M.I. =0 2.0)                                                     Example 4                                                                            Ethylene-Acrylic                                                                        Ethylene-Vinyl                                                      Acid Copolymer                                                                          Acetate Copoly-                                                     (Acrylic acid 20                                                                        mer (Vinyl Ace-                                                                         540   1500                                                wt.%, M.I. = 3.5)                                                                       tate 10 wt.%,                                                                 M.I. = 2.0)                                                  Example 5                                                                            Ethylene-Acrylic                                                                        Ethylene-Vinyl                                                      Acid Copolymer                                                                          Acetate Copoly-                                                     (Acrylic acid 10                                                                        mer (Vinyl Ace-                                                                         560   2600                                                wt.%, M.I. = 2.0)                                                                       tate 5 wt.%,                                                                  M.I. = 2.0)                                                  Example 6                                                                            Saline A-1650                                                                           Polyethylene                                                                  (Corona treated                                                                         550   3200                                                          surface)                                                     Reference                                                                     Example 1                                                                            Saline A-1601                                                                 single layer        600    240                                         Example 2                                                                            Polyethylene                                                                  single layer        200   1000                                         Example 3                                                                            Evaplex 660                                                                   single layer        340   1500                                         __________________________________________________________________________     NOTE: M.I. in the Table designated Melt Index (g/10 min) measured in          accordance with ASTM-D-1238.                                             

Each sample in the reference examples was obtained by bonding a singlelayer film with a metallic foil.

As is apparent from the above-mentioned examples and reference examples,in the plastic laminated metallic foil according to the presentinvention, its plastic layer had not only excellent adhesiveness withrespect to the metallic foil, but also the outer surface polyethylenejacket as well. Accordingly, even when a cable to which the plasticlaminated metallic foil of the present invention was applied was bent,there was no tearing off of each material.

Each sample in the reference examples had a certain degree ofadhesiveness with respect to either material. But with respect to othermaterials, the sample film had very low adhesiveness. Hence, afterapplying the film on a cable after it was bent, each material was easilytorn off.

EXAMPLES 7-9 and Reference Examples 4-7

Experiments were carried out along those lines of Examples 1-6 andReference Examples 1-3. The results obtained therefrom are indicated inTable 2, which follows:

                                      TABLE 2                                     __________________________________________________________________________           Plastic Film Constituting Component                                           Aluminum Foil                                                                 Side                                                                          (First Layer)                                                                           (Second Layer                                                       Ethylene-Un-                                                                            Ethylene-Un-                                                        saturated Car-                                                                          saturated Car-                                                                          Results of Test                                           boxylic Acid                                                                            boxylic Ester                                                                           A-Method                                                                            B-Method                                            Copolymer Copolymer (g/10 cm)                                                                           (g/10 cm)                                    __________________________________________________________________________    Example 7                                                                            Ionomer Resin                                                                           Ethylene-Ethyl                                                      Salin A-1650                                                                            Acrylate Copolymer                                                  (Trade Name,                                                                            DPDB-6169 (Trade                                                                        500   3200                                                manufactured                                                                            Name, manufac-                                                      by DuPont Co.)                                                                          tured by U.C.C.Co.)                                          Example 8                                                                            Saline A-1602 A;                                                                        Ethylene-Ethyl                                                      Ionomer contain-                                                                        Acrylate Copoly-                                                    ing an ethylene-                                                                        mer Zeterfine 30                                                    acrylic acid co-                                                                        (Trade Name,                                                        polymer as a base                                                                       manufactured by                                                                         520   3800                                                and obtained by                                                                         Dow Chemical Co.)                                                   using Na salt                                                                           Ethyl Acrylate 30                                                   M.I. = 1.3                                                                              wt. %                                                        Example 9                                                                            Ethylene-Acrylic                                                                        Ethylene-Ethyl                                                      Acid Copolymer;                                                                         Acrylate Copoly-                                                    DQDA-2609 mer (Zeterfine                                                      (Trade Name,                                                                            35, Dow Chemical                                                                        570   3200                                                manufactured by                                                                         Co.), Ethyl                                                         U. C. C. Co.)                                                                           Acrylate 35 wt.                                                     Acrylic Acid ca.                                                                        %                                                                   10 wt. % M.I. =2.0                                                     Reference                                                                     Example 4                                                                            Saline A-1650                                                                 Single Layer        600    240                                         Example 5                                                                            Ethylene-Ethyl                                                                Acrylate Copolymer                                                            Single Layer        550    650                                                (DPDB-6169)                                                            Example 6                                                                            Ethylene-Acrylic                                                              Acid Copolymer                                                                Single Layer        700   1050                                                (DQDA-2609)                                                                   Acrylic Acid ca 10                                                            wt.% M.I. = 2.0                                                        Example 7                                                                            Polyethylene        200   1000                                                Single Layer                                                           __________________________________________________________________________

The results of the experiments were substantially the same as inExamples 1-6 and Reference Examples 1-3, inclusive.

EXAMPLES 10-12 and Reference Examples 8-10

Experiments were carried out along these lines of Examples 1-6 andReference Examples 1-3. The results obtained therefrom are indicated inTable 3, which follows.

                                      TABLE 3                                     __________________________________________________________________________           Plastic Film                                                                  Ethylene-Unsaturated                                                                       Ethylene-Unsaturated                                                                       Result of Test                                      Carboxylic Ester Co-                                                                       Carboxylic Acid Co-                                                                        A-Method                                                                            B-Method                                      polymer (First Layer)                                                                      polymer (Second Layer)                                                                     (g/10 cm)                                                                           (g/10 cm                               __________________________________________________________________________    Example 10                                                                           Ethylene-Ethyl Acryl-                                                                      Ionomer Resin Saline                                             ate Copolymer DPDB-                                                                        A-1650 (Trade Name,                                                                        500   3200                                          6169 (Trade Name,                                                                          manufactured by Du                                               manufactured by                                                                            Pont Co.)                                                        U. C. C. Co.)                                                          Example 11                                                                           Ethylene-Ethyl Acryl-                                                                      Ionomer Resin                                                    ate Copolymer                                                                              Saline A-1650 (Trade                                             Zeterfine 30 (Trade                                                                        Name, manufactured                                                                         520   3800                                          Name, manufactured                                                                         by DuPont Co.)                                                   by Dow Chemical Co.)                                                   Example 12                                                                           Ethylene-Ethyl Acryl-                                                                      Ethylene-Acrylic Acid                                            ate Copolymer                                                                              Copolymer DQDA-                                                  Zeterfine 35 2609 (Trade Name,                                                                          570   3200                                                       manufactured by                                                               U. C. C. Co.)                                             Reference                                                                     Example 8                                                                            Ionomer Resin, Single                                                         Layer Sheet (Saline A-                                                        1650)                     600    240                                   Example 9                                                                            Ethylene-Ethyl Acrylate                                                       Copolymer Single Layer                                                        Sheet (DPDB-6169)         550    650                                   Example 10                                                                           Ethylene-Acrylic Acid                                                         Copolymer Single Layer                                                        Sheet (DQDA-2609)         700   1050                                   __________________________________________________________________________

The results of the experiments were substantially the same as inExamples 1-6 and Reference Examples 1-3, inclusive.

In the above-described examples, when iron was employed as a metallicfoil, its adhesiveness (by B-method) was elevated by 10%, respectively.

Although the present invention has been adequately described in theforegoing specification and examples included therein, it is readilyapparent that various modifications and changes may be made withoutdeparting from the scope thereof.

What is claimed is:
 1. A plastic laminated metallic foil useful as anelectrostatic shiledling layer and moisture-proofing layer for cablesconsisting essentially of:(a) a metallic foil composed of a memberselected from the group consisting of aluminum, copper, iron, steel,silver, gold and tin; (b) a first layer of an ionomer having a molecularweight of from 10,000 to 50,000 consisting essentially of a basecopolymer selected only from the group consisting of (1)ethylene-unsaturated carboxylic acid copolymers containing from 50 to 98weight % ethylene and from 50 to 2% acid, and (2) ethylene-unsaturatedcarboxylic acid-unsaturated carboxylic acid ester ternary copolymerscontaining from 50 to 98 weight % ethylene and from 50 to 2 weight % ofthe acid and ester wherein no more than 20 weight %, based upon theweight of ethylene, of the ester is present in said ternary copolymer;and (c) a second layer of a polymer having a molecular weight of from10,000 to 50,000 consisting essentially of a member selected only fromthe group consisting of ethylene-vinyl acetate copolymers containing nomore than 30 weight % vinyl acetate, and ethylene-unsaturated carboxylicacid ester copolymers containing no more than 95 weight % of the ester;said first layer being laminated onto and bonded to at least one surfaceof said metallic foil and said second layer being further laminated ontoand bonded to the outer surface of the laminated first layer, saidsecond layer being characterized by adhesivity toward said first layerand toward polyolefin of the type used for jacketing conductive cables,the total thickness of the first and second layers ranging from 45 to 75microns, and the thickness of said second layer ranging from 20 to 30microns.
 2. The plastic laminated metallic foil of claim 1, wherein saidmetallic foil is composed of aluminum.
 3. The plastic laminated metallicfoil of claim 1, wherein said unsaturated carboxylic acid is anunsaturated aliphatic carboxylic acid containing 2-12 carbon atoms otherthan those carbon atoms contained in its carboxyl group.
 4. The plasticlaminated metallic foil of claim 3, wherein said unsaturated carboxylicacid is a member selected from the group consisting of a mono- anddivalent carboxylic acid.
 5. The plastic laminated metallic foil ofclaim 1, wherein said unsaturated carboxylic acid is one selected fromthe group consisting of acrylic acid, methacrylic acid, itaconic acid,and maleic anhydride.
 6. The plastic laminated metallic foil of claim 1,wherein said unsaturated carboxylic acid is acrylic acid.
 7. The plasticlaminated metallic foil of claim 1, wherein the amount of ethylene andthe carboxylic acid in said ethylene-unsaturated carboxylic acidcopolymers ranges from 70 to 90% by weight and from 30 to 10% by weight,respectively.
 8. The plastic laminated metallic foil of claim 1, whereinsaid unsaturated carboxylic ester is a member selected from the groupconsisting of ethyl, propyl, and butyl esters of an aliphaticunsaturated acid containing 2-12 carbon atoms, other than those carbonatoms contained in its carboxyl group.
 9. The plastic laminated metallicfoil of claim 8, wherein said unsaturated carboxylic ester is the esterof a mono- or divalent unsaturated carboxylic acid.
 10. The plasticlaminated metallic foil of claim 8, wherein said unsaturated carboxylicester is a member selected from the group consisting of acrylic andmethacrylic esters.
 11. The plastic laminated metallic foil of claim 8,wherein said unsaturated carboxylic ester is ethyl acrylate.
 12. Theplastic laminated metallic foil of claim 1, wherein said ionomercontains a metal ion selected from the group consisting of magnesium,strontium, sodium, and zinc ions.
 13. The plastic laminated metallicfoil of claim 12, wherein said ionomer consists essentially of anethylene acrylic acid copolymer as said base and a zinc ion as saidmetal ion.
 14. The plastic laminated metallic foil of claim 15, whereinsaid ionomer consists essentially of an ethylene-acrylic acid copolymeras said base and a sodium ion as said metal ion.
 15. The plasticlaminated metallic foil of claim 1, wherein said ethylene-vinyl acetatecopolymer has a vinyl acetate content which ranges from 2 to 20% byweight.
 16. The plastic laminated metallic foil of claim 1, wherein saidethylene-unsaturated carboxylic ester copolymer has an unsaturatedcarboxylic ester content which ranges from 1 to 95% by weight.
 17. Theplastic laminated metallic foil according to claim 16, wherein saidethylene-unsaturated carboxylic ester copolymer has an unsaturatedcarboxylic ester content which ranges from 1 to 85% by weight.
 18. Theplastic laminated metallic foil of claim 1, wherein the surface of thefirst polymer layer is subjected to an adhesion treatment.
 19. Theplastic laminated metallic foil of claim 18, wherein the adhesiontreatment is perfected through Corona discharge.
 20. The plasticlaminated metallic foil of claim 18, wherein the adhesion treatment isperfected through an oxidizing flame.
 21. The plastic laminated metallicfoil of claim 18, wherein the adhesion treatment is perfected throughchromic acid.
 22. The plastic laminated metallic foil of claim 1,wherein the thickness of the metallic foil ranges from 100-250 μ. 23.The plastic laminated metallic foil of claim 1, wherein said first andsecond layers comprise simultaneously extruded layers.
 24. The plasticlaminated metallic foil of claim 23, wherein said first and secondlayers are thermally pressed together.
 25. The plastic laminatedmetallic foil of claim 1 consisting essentially of said metallic foiland, on only one surface thereof, said first and said second layers,said second layer being in intimate contact with and strongly bonded tosaid first layer and said first layer being in intimate contact with andstrongly bonded to said surface of said metallic foil.
 26. The plasticlaminated metallic foil of claim 1 consisting essentially of said firstand said second layers on both surfaces of said metallic foil, each ofsaid second layers being in intimate contact with and strongly bonded toeach of said first layers and each of said first layers being in turn inintimate contact with and strongly bonded to both of said surfaces ofsaid metallic foil.
 27. The plastic laminated metallic foil of claim 1wherein said base copolymer of said ionomer is said ethylene-unsaturatedcarboxylic acid copolymer and said polymer of said second layer is saidethylene-unsaturated carboxylic acid ester copolymer.